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Volume of Pipette = 25.0 cm³
| Burette Readings (cm³) | 1st Time | 2nd Time | 3rd Time |
|---|---|---|---|
| Final Readings | 13.00 | 13.10 | 13.20 |
| Initial Readings | 0.00 | 0.00 | 0.00 |
| Volume of Acid Used | 13.00 | 13.10 | 13.20 |
1a. Average Volume of A Used, VA
VA =
(13.00 + 13.10 + 13.20) / 3
= 13.10 cm³
1b. Concentration of KOH
CB = ? mol dm-3
VB = 25.0 cm³
Equation:
CH3COOH + KOH → CH3COOK + H2O
nA = 1
nB = 1
Continuation of 1(bi)
Using the formula:
CBVB nA
———— = ——
CAVA. nB
CB =
(CA × VA × nB) /
(VB × nA)
CB =
(0.1 × 13.1 × 1) /
(25 × 1)
CB =
13.1 / 250
CB = 0.0524 mol dm-3
1(bii) Concentration of B in g/dm³
Mass Concentration = Molar Concentration × Molar Mass
Molar Mass of KOH:
K = 39
O = 16
H = 1
Molar Mass = 39 + 16 + 1
= 56 g/mol
Mass Concentration of KOH in B:
= 0.0524 × 56
= 2.93 g/dm³
Continuation of 1(biv)
Amount (Moles) of Ethanoic Acid
Using the formula:
n = CV
n =
(0.1 × 13.1) / 1000
n = 0.00131 mol
From the equation:
CH3COOH + KOH → CH3COOK + H2O
1 mole of CH3COOH produces 1 mole of H2O
Therefore:
0.00131 mol of CH3COOH produces
0.00131 mol of H2O
Using:
Number of molecules = Number of moles × Avogadro’s constant
Number of H2O molecules =
0.00131 × 6.02 × 1023
= 7.8 × 1020 molecules
| QUESTION 2 | ||
|---|---|---|
| TEST | OBSERVATION | INFERENCE |
| (a) Sample C + few cm³ of dilute acid + filter | Effervescence occurs with the release of a colourless, odourless gas which turns lime water milky.
A clear or colourless filtrate and a white residue were obtained. |
The gas is CO₂.
CO₃²⁻ ion present. The solution is a mixture of a soluble and insoluble substance. |
| (b)(i) First portion + NaOH in drops, then in excess | White (chalky) precipitate is formed.
Precipitate dissolves to give a clear or colourless solution. |
Pb²⁺ or Ca²⁺ ions present.
Pb²⁺ ions present. |
| (b)(ii) Another portion + NH₃ in drops, then in excess | White chalky precipitate is formed.
Precipitate remains insoluble in excess. |
Pb²⁺ ion present. |
| (c) Residue + 2 cm³ of distilled H₂O | — | — |
(3a)
Complete the table
Under; Apparatus
(i) Measuring cylinder (or Pipette / Burette)
(ii) Clay triangle
(iii) Crucible
(iv) Bomb calorimeter
Under; Use
(i)For measuring specific volume of a liquid
(ii)To support a crucible being heated by a Bunsen burner
(iii)As container for melting and heating to a very high temperature
(iv)To measure the heat of combustion of a particular reaction
(3b)
(i)PbSO⁴ (Insoluble)
(ii)PbCl² (slightly soluble in cold water, soluble in hot water
(iii)Pb(NO³)² (soluble)
Order; PbSO⁴ <PbCl² <Pb (NO³)²
(3c)
(i)KNO³(aq); No effect. It is a neutral salt formed from strong acid (HNO³) and a strong base (KOH)
(ii)K²CO³; turns red litmus blue. It is a basic salt formed from a weak acid (H²CO³) and strong base (KOH)
(iii)Al²(SO⁴)³(aq); turns blue litmus red. It is an acidic salt; aluminium ions undergo hydrolysis in water to produce H+ ions

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